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Beilstein J. Nanotechnol. 2017, 8, 485–493, doi:10.3762/bjnano.8.52
Figure 1: Structure of phosphine oxide derivatives 1–3, of ox-MWCNTs 4 and of GPs 5.
Scheme 1: The Tour reaction applied on CNMs 4 and 5.
Scheme 2: The [1 + 2] nitrene cycloaddition on CNMs 4 and 5.
Scheme 3: The Tour reaction with 4-azido aniline (10) on CNMs 4 and 5 and the subsequent CuAAC reaction.
Figure 2: Fitting of the XPS spectrum characteristic of P collected on GPs-Nit-PO 9 showing the two component...
Figure 3: Raman spectra: GPs 5 vs GPs-Nit-PO 9 (top), ox-MWCNTs 4 vs ox-MWCNTs-Nit-PO 8 (bottom).
Figure 4: TEM images of ox-MWCNTs 4 (1), ox-MWCNTs-PO 6 (2), ox-MWCNTs-Nit-PO 8 (3), GPs 5 (4) GPs-PO 7 (5), ...
Scheme 4: Reduction of phosphine oxide 6 to the corresponding phosphine 6-red.
Figure 5: XPS analysis of samples form the reduction reaction of compound 6: starting material (top), after 2...
Scheme 5: The Staudinger ligation reaction performed with benzoic acid (15) or cinnamic acid (18), and benzyl...